Polisetty, V G and Jampana, Phanindra Varma
(2013)
State Estimation in Solid Oxide Fuel Cell(SOFC)System.
Masters thesis, Indian Institute of Technology, Hyderabad.
Abstract
Solid oxide fuel cells (SOFCs) oer a clean, low pollution technology to electrochemically
generate electricity at high eciency. An SOFC consists of a dense solid electrolyte and two
porous electrodes in contact with an interconnect on either side. The control of an SOFC
stack becomes important in order to ensure adequate and disturbance free electric power.
As several controlled/constrained variables are not directly measured in a stack, state
estimators can be used in order to study the dynamic behaviour of SOFC stacks as well as
to design eective SOFC controllers. In this thesis, A zero dimensional model represented
by a set of ordinary dierential equations is derived for dynamic modeling. The model
consists of molar balances and an energy balance coupled with a simplied description of
the fuel cell electrochemistry. The chemical species considered are H2 and H2O for fuel
side (anode side) and O2 and N2 for air side (cathode side) and the electrochemical model
accounts for ohmic, concentration and activation losses. Considering the estimation part,
the state vector which is to be estimated consists of partial pressure of chemical species and
temperature, with voltage as the measurement. Estimation of states for linear systems can
be done by Kalman Filter. States of nonlinear systems can be estimated using Extended
Kalman Filter(EKF), Unscented Kalman Filter (UKF). We choose UKF for non linear
state estimation. UKF is a derivative free state estimator for non linear systems. This
work investigates the use of non linear state estimator UKF to estimate the states of SOFC
system. This method can be applied to estimate states in any type of fuel cells (PEMFC,
AFC etc.) by very slight modications.
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