Transition-Metal Catalyzed Stereoselective γ-Arylation and Friedel-Crafts Alkylation: A Concise Synthesis of Indenes

Ramesh, Karu and Satyanarayana, Gedu (2020) Transition-Metal Catalyzed Stereoselective γ-Arylation and Friedel-Crafts Alkylation: A Concise Synthesis of Indenes. European Journal of Organic Chemistry, 2020 (22). pp. 3235-3242. ISSN 1434193X

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Abstract

A highly stereoselective [Pd]-catalyzed arylation of tert-alkenols, is presented and applied to the synthesis of indenes using intramolecular Friedel–Crafts alkylation sequence. The initial Heck reaction is performed by using water as the green solvent. A simple acid triggers intramolecular alkylation in short reaction times at room temperature. Notably, indenes have been accomplished using a single column chromatography technique.

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IITH Creators:	IITH Creators ORCiD Ramesh, Karu UNSPECIFIED Satyanarayana, Gedu UNSPECIFIED
Item Type:	Article
Uncontrolled Keywords:	Catalysis; Friedel–Crafts alkylation; Indenes; tert-Alkenols; γ-Arylation
Subjects:	Chemistry
Divisions:	Department of Chemistry
Depositing User:	. LibTrainee 2021
Date Deposited:	15 Jul 2021 06:32
Last Modified:	15 Jul 2021 06:32
URI:	http://raiithold.iith.ac.in/id/eprint/8333
Publisher URL:	http://doi.org/10.1002/ejoc.202000030
OA policy:	https://v2.sherpa.ac.uk/id/publication/1692
Related URLs:	Author

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