G, Satyanarayana and Suchand, Basuli
(2019)
Palladium-Catalyzed Direct Acylation: One-Pot Relay Synthesis of Anthraquinones.
Synthesis, 51 (03).
pp. 769-779.
ISSN 0039-7881
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Abstract
A bis-acylation strategy to access functionalized anthraquinones via one-pot relay process, is presented. The first acylation was feasible under [Pd]-catalyzed intermolecular direct acylation reaction, while, the second acylation was accomplished by using intramolecular Friedel–Crafts acylation. Notably, benchtop aldehydes have been utilized as non-toxic acylation agents in the key [Pd]-catalyzed acylation.
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