Ghosh, Ruma and D S, Sharada
(2016)
Transition-Metal-Free Direct C(sp3)-H Functionalization leading to Aza-γ-Carboline Alkaloid Analogues in Cascade Fashion.
Masters thesis, Indian Institute of Technology Hyderabad.
Abstract
Iodine promoted cascade reaction has been developed for the synthesis of unrivalled Aza-γ-carboline alkaloid analogues via C-H functionalization of 2H-indazoles. The construction of the product has been realized under metal-free condition via in situ formation of imine, transimination followed by cyclization. In this present method iodine played a triple role, in imine formation, transimination and imine activation. The key features of the present protocol are metal-free, peroxide-free, operational simplicity and wide
substrates scope.
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IITH Creators: |
IITH Creators | ORCiD |
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D S, Sharada | UNSPECIFIED |
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Item Type: |
Thesis
(Masters)
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Uncontrolled Keywords: |
Transition-metal free, Evironmentally friendly, Molecular iodine, TD503 |
Subjects: |
Chemistry |
Divisions: |
Department of Chemistry |
Depositing User: |
Library Staff
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Date Deposited: |
05 May 2016 05:07 |
Last Modified: |
22 May 2019 10:38 |
URI: |
http://raiithold.iith.ac.in/id/eprint/2316 |
Publisher URL: |
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Related URLs: |
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