Syntheses of the Hexahydroindene Cores of Indanomycin and Stawamycin by Combinations of Iridium-Catalyzed Asymmetric Allylic Alkylations and Intramolecular Diels–Alder Reactions

Gartner, M and G, Satyanarayana and Forster, S and Helmchen, G (2013) Syntheses of the Hexahydroindene Cores of Indanomycin and Stawamycin by Combinations of Iridium-Catalyzed Asymmetric Allylic Alkylations and Intramolecular Diels–Alder Reactions. Chemistry - A European Journal, 19 (1). pp. 400-405. ISSN 0947-6539

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Abstract

Short and concise syntheses of the hexahydroindene cores of the antibiotics indanomycin (X-14547 A) and stawamycin are presented. Key methods used are an asymmetric iridium-catalyzed allylic alkylation, a modified Julia olefination, a Suzuki–Miyaura coupling, and an intramolecular Diels–Alder reaction.

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IITH Creators:	IITH Creators ORCiD G, Satyanarayana UNSPECIFIED
Item Type:	Article
Uncontrolled Keywords:	alkylation; Diels–Alder reaction; hexahydroindenes; iridium; Julia olefination; Suzuki–Miyaura coupling
Subjects:	?? sub5.8 ??
Divisions:	Department of Chemistry
Depositing User:	Team Library
Date Deposited:	29 Dec 2014 09:14
Last Modified:	24 Sep 2015 10:13
URI:	http://raiithold.iith.ac.in/id/eprint/1265
Publisher URL:	http://dx.doi.org/10.1002/chem.201202822
OA policy:	http://www.sherpa.ac.uk/romeo/issn/0947-6539/
Related URLs:	Google Scholar

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