Transition-Metal Catalyzed Stereoselective γ-Arylation and Friedel-Crafts Alkylation: A Concise Synthesis of Indenes

Ramesh, Karu and Satyanarayana, Gedu (2020) Transition-Metal Catalyzed Stereoselective γ-Arylation and Friedel-Crafts Alkylation: A Concise Synthesis of Indenes. European Journal of Organic Chemistry, 2020 (22). pp. 3235-3242. ISSN 1434193X

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Abstract

A highly stereoselective [Pd]-catalyzed arylation of tert-alkenols, is presented and applied to the synthesis of indenes using intramolecular Friedel–Crafts alkylation sequence. The initial Heck reaction is performed by using water as the green solvent. A simple acid triggers intramolecular alkylation in short reaction times at room temperature. Notably, indenes have been accomplished using a single column chromatography technique.

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IITH Creators:
IITH CreatorsORCiD
Ramesh, KaruUNSPECIFIED
Satyanarayana, GeduUNSPECIFIED
Item Type: Article
Uncontrolled Keywords: Catalysis; Friedel–Crafts alkylation; Indenes; tert-Alkenols; γ-Arylation
Subjects: Chemistry
Divisions: Department of Chemistry
Depositing User: . LibTrainee 2021
Date Deposited: 15 Jul 2021 06:32
Last Modified: 15 Jul 2021 06:32
URI: http://raiithold.iith.ac.in/id/eprint/8333
Publisher URL: http://doi.org/10.1002/ejoc.202000030
OA policy: https://v2.sherpa.ac.uk/id/publication/1692
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