Formation of bi-aryls via a domino palladium catalysis

J, Krishna and A, Gopi Krishna Reddy and G, Satyanarayana (2014) Formation of bi-aryls via a domino palladium catalysis. Tetrahedron Letters, 55 (4). pp. 861-864. ISSN 0040-4039

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Abstract

Synthesis of bi-aryls via a domino Pd-catalyzed reaction of 1-(2-bromophenyl)-2-methylpropan-1-ones/(2-bromophenyl)(cyclohexyl)methanones is presented. The mechanism of the reaction is believed to proceed through a five membered palladacycle that combines with a second molecule of halo-arene to yield the bi-aryls. This method is quite successful to deliver highly sterically crowded bi-aryls with dense functionalities on the aromatic rings.

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IITH Creators:	IITH Creators ORCiD G, Satyanarayana UNSPECIFIED
Item Type:	Article
Uncontrolled Keywords:	[Pd]-catalysis; Bi-aryls; Domino; 1-(2-Bromophenyl)-2-methylpropan-1-ones; (2-Bromophenyl)(cyclohexyl)methanones
Subjects:	?? sub5.8 ??
Divisions:	Department of Chemistry
Depositing User:	Team Library
Date Deposited:	29 Dec 2014 06:26
Last Modified:	24 Sep 2015 10:21
URI:	http://raiithold.iith.ac.in/id/eprint/1260
Publisher URL:	http://dx.doi.org/10.1016/j.tetlet.2013.12.030
OA policy:	http://www.sherpa.ac.uk/romeo/issn/0040-4039/
Related URLs:	Google Scholar

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