Alkali and Alkaline Earth Metal Complexes as Versatile Catalysts for Ring-Opening Polymerization of Cyclic Esters

Bhattacharjee, J. and Panda, Tarun K and et al, . (2021) Alkali and Alkaline Earth Metal Complexes as Versatile Catalysts for Ring-Opening Polymerization of Cyclic Esters. The Chemical Record, 21 (8). pp. 1898-1911. ISSN 1527-8999

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Abstract

Biodegradable polyesters such as poly(ϵ-caprolactone) (PCL) and poly(lactic acid) (PLA) have been considered for use in several areas, such as drug delivery devices, sutures, tissue engineering, and GBR membranes, due to its bio-renewability, biodegradability, and biocompatibility. Several synthetic techniques for the preparation of polyesters have been reported in the literature, amongst which the ring-opening polymerization (ROP) of cyclic esters is the most efficient. A convenient approach to access iso-selective PLAs is polymerization of racemic lactide (rac-LA), which shows excellent stereoregularity without the need for costly chiral auxiliaries or ligands. In this personal account, we review a series of methods that have been practiced to the synthesis of biodegradable polyesters from various cyclic monomers using alkali and alkaline earth metal complexes as efficient catalysts.

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IITH Creators:
IITH CreatorsORCiD
Panda, Tarun Khttp://orcid.org/0000-0003-0975-0118
Item Type: Article
Subjects: Chemistry
Divisions: Department of Chemistry
Depositing User: Mrs Haseena VKKM
Date Deposited: 11 Feb 2022 05:35
Last Modified: 11 Feb 2022 09:25
URI: http://raiithold.iith.ac.in/id/eprint/9155
Publisher URL: https://onlinelibrary.wiley.com/doi/abs/10.1002/tc...
OA policy: https://v2.sherpa.ac.uk/id/publication/6659?templa...
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