Propargyl alcohols as alkyne sources: Synthesis of heterocyclic compounds under microwave irradiation

Ramesh, Karu and Satyanarayana, Gedu (2020) Propargyl alcohols as alkyne sources: Synthesis of heterocyclic compounds under microwave irradiation. Journal of Organometallic Chemistry, 922. p. 121350. ISSN 0022328X

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Abstract

Fused heterocyclic compounds with alkyne substituent, have been achieved using a domino microwave-assisted [Pd]-catalysis. Interestingly, tert-propargyl alcohols underwent a selective degradative β-carbon cleavage and served as masked alkynyl equivalents, in water as the sole reaction medium. Dihydrobenzofurans, indolines, and oxindoles have been accomplished using this dual C–C bond-forming strategy.

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IITH Creators:	IITH Creators ORCiD Ramesh, Karu UNSPECIFIED Satyanarayana, Gedu UNSPECIFIED
Item Type:	Article
Uncontrolled Keywords:	Alkynyls; Bond forming; Dihydrobenzofurans; Heterocyclic compound; Microwave assisted; Oxindoles; Propargyl alcohol; Reaction medium
Subjects:	Chemistry
Depositing User:	. LibTrainee 2021
Date Deposited:	15 Jul 2021 06:20
Last Modified:	15 Jul 2021 06:20
URI:	http://raiithold.iith.ac.in/id/eprint/8332
Publisher URL:	http://doi.org/10.1016/j.jorganchem.2020.121350
OA policy:	https://v2.sherpa.ac.uk/id/publication/12833
Related URLs:	Author

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