Alkali and Alkaline Earth Metal Complexes as Versatile Catalysts for Ring‐Opening Polymerization of Cyclic Esters

Bhattacharjee, Jayeeta and Sarkar, Alok and Panda, Tarun K. (2021) Alkali and Alkaline Earth Metal Complexes as Versatile Catalysts for Ring‐Opening Polymerization of Cyclic Esters. The Chemical Record. ISSN 1527-8999

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Abstract

Biodegradable polyesters such as poly(ϵ-caprolactone) (PCL) and poly(lactic acid) (PLA) have been considered for use in several areas, such as drug delivery devices, sutures, tissue engineering, and GBR membranes, due to its bio-renewability, biodegradability, and biocompatibility. Several synthetic techniques for the preparation of polyesters have been reported in the literature, amongst which the ring-opening polymerization (ROP) of cyclic esters is the most efficient. A convenient approach to access iso-selective PLAs is polymerization of racemic lactide (rac-LA), which shows excellent stereoregularity without the need for costly chiral auxiliaries or ligands. In this personal account, we review a series of methods that have been practiced to the synthesis of biodegradable polyesters from various cyclic monomers using alkali and alkaline earth metal complexes as efficient catalysts.

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IITH Creators:
IITH CreatorsORCiD
Bhattacharjee, JayeetaUNSPECIFIED
Sarkar, AlokUNSPECIFIED
Panda, Tarun Khttp://orcid.org/0000-0003-0975-0118
Item Type: Article
Uncontrolled Keywords: Alkali and Alkaline Earth ,Metal Complexes as Versatile Catalysts,Polymerization of Cyclic Esters
Subjects: Chemistry
Divisions: Department of Chemistry
Depositing User: . LibTrainee 2021
Date Deposited: 06 Jul 2021 05:07
Last Modified: 06 Jul 2021 05:07
URI: http://raiithold.iith.ac.in/id/eprint/8121
Publisher URL: http://doi.org/10.1002/tcr.202100148
OA policy: https://v2.sherpa.ac.uk/id/publication/6659
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