SYNTHESIS, CRYSTAL STRUCTURE AND THERMAL STUDIES OF TRIPHENYLSILANOL-PIPERAZINE ADDUCT
Dinesh, M. and Kavitha, V. and Prabusankar, G. and Babu, B. and babu, B. Mohan and Donghui, G. and Maadeswaran, P. (2020) SYNTHESIS, CRYSTAL STRUCTURE AND THERMAL STUDIES OF TRIPHENYLSILANOL-PIPERAZINE ADDUCT. Rasayan Journal of Chemistry, 13 (04). pp. 2294-2301. ISSN 09741496
Full text not available from this repository. (Request a copy)Abstract
The solid-state structure of triphenylsilanol-piperazine adduct was reported from optimized reaction conditions. The molecular composition was further supported by elemental analysis, FT-IR, multinuclear NMR (1H and13C) and TGA. In solid-state, the four triphenylsilanols are associated in tetrameric form with one piperazine molecule through intra and intermolecular hydrogen bonds that lead to the new type of hydrogen bonding. The molecule represents one of the rare examples of triphenylsilanol-amine derivatives with a new hydrogen-bonding pattern.
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| Item Type: | Article | ||||
| Uncontrolled Keywords: | Co-crystal; Crystal Structure; Hydrogen bond; Organosilicon; Piperazine; Triphenylsilanol | ||||
| Subjects: | Chemistry Chemistry > Inorganic chemistry Chemistry > Organic chemistry |
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| Divisions: | Department of Chemistry | ||||
| Depositing User: | . LibTrainee 2021 | ||||
| Date Deposited: | 21 Jun 2021 10:48 | ||||
| Last Modified: | 24 Feb 2022 11:07 | ||||
| URI: | http://raiithold.iith.ac.in/id/eprint/7963 | ||||
| Publisher URL: | http://doi.org/10.31788/RJC.2020.1345643 | ||||
| OA policy: | https://iith.irins.org/profile/62213 | ||||
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