Chalcogen Bonding Induced Tetraselenides from Twisted Diselenides
Vaddamanu, Moulali and Prabusankar, Ganesan (2020) Chalcogen Bonding Induced Tetraselenides from Twisted Diselenides. European Journal of Inorganic Chemistry, 2020 (25). pp. 2403-2407. ISSN 14341948
Full text not available from this repository. (Request a copy)Abstract
The first sterically controlled oxidation of mesoionic selone using copper(II) salt was demonstrated. The present methodology gave access to a rare tetraselenide from dimerized diselenides through chalcogen bonding (ChB). Besides, a similar approach with sterically less crowded mesoionic triazole selone, 1-(2-mesitylene)-3-methyl-4-phenyltriazolin-5-selone, gave the classic diselenide salt. In the solid state, these new selenide salts demonstrate a unique structural aggregation with unusual bonding features such as Se···O and Se···F interactions.
| IITH Creators: |
|
||||||
|---|---|---|---|---|---|---|---|
| Item Type: | Article | ||||||
| Uncontrolled Keywords: | Chalcogen bonding; Main group elements; Mesoionic compounds; Secondary bonding interactions; Selenium | ||||||
| Subjects: | Chemistry Chemistry > Inorganic chemistry Chemical Engineering Chemical Engineering > Oils, fats, waxes, gases |
||||||
| Divisions: | Department of Chemistry | ||||||
| Depositing User: | . LibTrainee 2021 | ||||||
| Date Deposited: | 21 Jun 2021 09:59 | ||||||
| Last Modified: | 21 Jun 2021 09:59 | ||||||
| URI: | http://raiithold.iith.ac.in/id/eprint/7959 | ||||||
| Publisher URL: | http://doi.org/10.1002/ejic.202000275 | ||||||
| OA policy: | https://v2.sherpa.ac.uk/id/publication/1687 | ||||||
| Related URLs: |
Actions (login required)
 |
View Item |
|
Statistics for this ePrint Item |
Altmetric
Altmetric