Facile reduction of carboxylic acids to primary alcohols under catalyst-free and solvent-free conditions

Harinath, Adimulam and Bhattacharjee, Jayeeta and Panda, Tarun K. (2019) Facile reduction of carboxylic acids to primary alcohols under catalyst-free and solvent-free conditions. Chemical Communications, 55 (10). pp. 1386-1389. ISSN 1359-7345

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Abstract

We report the development of a facile protocol for the deoxygenative hydroboration of aliphatic and aryl carboxylic acids to afford corresponding primary alcohols under solvent-free and catalyst-free conditions. The reaction proceeds under ambient temperature exhibits good tolerance towards various functional groups and generates quantitative yields. The plausible mechanism involves the formation of Lewis acid-base adducts as well as the liberation of hydrogen gas.

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IITH Creators:

IITH Creators	ORCiD
Harinath, Adimulam	UNSPECIFIED
Bhattacharjee, Jayeeta	UNSPECIFIED
Panda, Tarun K	http://orcid.org/0000-0003-0975-0118

Item Type:

Article

Uncontrolled Keywords:

Article; catalyst; chemical reaction; clinical protocol; deoxygenation; environmental temperature; hydroboration; quantitative analysis; alcohol; aliphatic dicarboxylic acid; carboxylic acid; hydrogen; Lewis acid; solvent

Subjects:

Chemistry
Chemistry > Inorganic chemistry
Chemistry > Organic chemistry

Divisions:

Department of Chemistry

Depositing User:

. LibTrainee 2021

Date Deposited:

16 Jun 2021 06:58

Last Modified:

16 Jun 2021 06:58

URI:

http://raiithold.iith.ac.in/id/eprint/7922