Heterogeneous Direct Acylation Strategy to Diaryl Ketones and Their Application to 1, 3‐Dihydroisobenzofurans

Bhattacharya, Trisha and Suchand, Basuli and Ch, Subrahmanyam and G, Satyanarayana and et al, . (2020) Heterogeneous Direct Acylation Strategy to Diaryl Ketones and Their Application to 1, 3‐Dihydroisobenzofurans. ChemistrySelect, 5 (4). pp. 1349-1352. ISSN 2365-6549

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Abstract

Aromatic acylation is an indispensable chemical transformation in organic synthesis in affording aryl ketones. In this manuscript, we have described the synthesis of aromatic ketones utilizing graphene oxide (GO) supported PdO nanoparticles (PdO/GO), as heterogeneous transition metal catalyst. The [Pd]‐heterogeneous catalyst enabled the coupling between iodoarenes and aromatic aldehydes. The acylation was carried out by eliminating toxic CO gas as the source of the carbonyl. Further, practicality of this strategy was also demonstrated by fusing 1,3‐dihydroisobenzofurans.

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IITH Creators:	IITH Creators ORCiD Ch, Subrahmanyam https://orcid.org/0000-0002-2643-3854 G, Satyanarayana UNSPECIFIED
Item Type:	Article
Subjects:	Chemistry
Divisions:	Department of Chemistry
Depositing User:	Team Library
Date Deposited:	29 Jan 2020 04:55
Last Modified:	29 Jan 2020 04:55
URI:	http://raiithold.iith.ac.in/id/eprint/7375
Publisher URL:	http://doi.org/10.1002/slct.201903963
Related URLs:	Google Scholar

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