A, Daya Mani and Xanthopoulos, N and Laub, D and Ch, Subrahmanyam
(2014)
Combustion synthesis of cadmium sulphide nanomaterials for efficient visible light driven hydrogen production from water.
Journal of Chemical Sciences, 126 (4).
pp. 967-973.
ISSN 0974-3626
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Abstract
Anion-doped cadmium sulphide nanomaterials have been synthesized by using combustion method at normal atmospheric conditions. Oxidant/fuel ratios have been optimized in order to obtain CdS with best characteristics. Formation of CdS and size of crystallite were identified by X-ray diffraction and confirmed by transmission electron microscopy. X-ray photoelectron spectroscopy confirmed the presence of C and N in the CdS matrix. The observed enhanced photocatalytic activity of the CdS nanomaterials for the hydrogen production from water (2120 μmol/h) can be attributed to high crystallinity, low band gap and less exciton recombination due to the C and N doping.
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