Synthesis and Crystal structure of BaIn2Te4

Nishad, Abhishek Kumar and Jai, Prakash (2019) Synthesis and Crystal structure of BaIn2Te4. Masters thesis, Indian institute of technology Hyderabad.

[img] Text
MSc_Thesis_TD1363_2019.docx
Restricted to Repository staff only until 20 November 2019.

Download (1MB) | Request a copy

Abstract

By using solid-state sealed tube method, the single crystals of alkaline earth metal based chalcogenide, BaIn2Te4 were grown at 1173 K. The polycrystalline BaIn2Te4 was also successfully synthesized in bulk at 1123 K by a two- step sealed tube method. The single phase nature of BaIn2Te4 was confirmed by powder X-ray diffraction pattern. From the single crystal X-ray diffraction studies, we have found that the BaIn2Te4 crystallizes in a D_2h^20Cccm space group in the orthorhombic crystal system with cell dimensions of a = 7.1417(14) Å, b =12.034(2) Å, and c =12.107(2) Å with Z = 4. The crystal structure of BaIn2Te4 is related to the tetragonal binary TlSe structure (space group: I4/mcm). The main structural features of this structure are one dimensional chains of 1¦∞[In2Te42] that are made up of edge sharing InTe4 tetrahedra, and Ba2+ cations that act as a space filler. The 1¦∞[In2Te42] chains are separated by barium atoms that are eight–coordinated with tellurium atoms forming a distorted square antiprism like geometry. This ternary compound does not feature any homoatomic bonding, and so formal oxidation states of atoms can be simply assigned as Ba2+, In3+, and Te2. This indicates that BaIn2Te4 has a closed-shell electronic configuration and belongs to the Zintl family of compounds.

[error in script]
IITH Creators:
IITH CreatorsORCiD
Jai, PrakashUNSPECIFIED
Item Type: Thesis (Masters)
Subjects: Chemistry
Divisions: Department of Chemistry
Depositing User: Team Library
Date Deposited: 20 May 2019 10:49
Last Modified: 20 May 2019 10:49
URI: http://raiithold.iith.ac.in/id/eprint/5263
Publisher URL:
Related URLs:

    Actions (login required)

    View Item View Item
    Statistics for RAIITH ePrint 5263 Statistics for this ePrint Item