Synthesis and Crystal Structure of Cs2 U2 (P2 Se9 )(Se2 )2

Mesbah, Adel and Jai, Prakash and Beard, Jessica C and Lebègue, Sébastien and Ibers, James A (2018) Synthesis and Crystal Structure of Cs2 U2 (P2 Se9 )(Se2 )2. Journal of Inorganic and General Chemistry, 644 (22). pp. 1480-1484. ISSN 0044-2313

Full text not available from this repository. (Request a copy)

Abstract

Black single crystals of Cs2U2(P2Se9)(Se2)2 were synthesized at 1023 K by a solid‐state reaction. Its structure was determined by single‐crystal X‐ray diffraction methods. The compound is isostructural with Rb2U2(P2Se9)(Se2)2 and Cs2Th2(P2Se9)(Se2)2 compounds, and crystallizes in the orthorhombic space group Pbca. Cs2U2(P2Se9)(Se2)2 displays a three‐dimensional structure comprising USe9 polyhedra connected via the Se22– and P2Se9 species with channels filled by Cs atoms. From electronic structure calculations the compound is found to be a metal with a ferromagnetic arrangement of the magnetic moments.

[error in script]

IITH Creators:	IITH Creators ORCiD Jai, Prakash UNSPECIFIED
Item Type:	Article
Subjects:	Chemistry
Divisions:	Department of Chemistry
Depositing User:	Team Library
Date Deposited:	08 Jan 2019 10:41
Last Modified:	08 Jan 2019 10:41
URI:	http://raiithold.iith.ac.in/id/eprint/4678
Publisher URL:	http://doi.org/10.1002/zaac.201800263
Related URLs:	Google Scholar

Actions (login required)

View Item

Statistics for this ePrint Item