Kinetics of electrochemical charge transfer in HT-PEM fuel cells

Unnikrishnan, Anusree and Rajalakshmi, Natarajan and Janardhanan, V (2018) Kinetics of electrochemical charge transfer in HT-PEM fuel cells. Electrochimica Acta. ISSN 0013-4686 (In Press)

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Abstract

This paper presents experimental and modeling study of high temperature polymer electrolyte membrane fuel cell performance. The experiments are performed using in-house prepared MEA with an active area of 2.25 cm2. The experiments are simulated using a one dimensional distributed charge transfer model that resolves the properties along the thickness of the MEA. Six different HOR models and two different ORR models are subjected to initial studies. The model predictions are compared with cell performance on pure H2 and H2 with CO contamination. A detailed sensitivity analysis is carried out to understand the influence of various model parameters on cell performance over a range of potentials.

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IITH Creators:
IITH CreatorsORCiD
Janardhanan, Vhttp://orcid.org/0000-0002-3458-4169
Item Type: Article
Uncontrolled Keywords: Kinetics, CO poisoning, Modeling, Experiments, HOR, ORR
Subjects: Chemical Engineering
Divisions: Department of Chemical Engineering
Depositing User: Team Library
Date Deposited: 10 Oct 2018 03:50
Last Modified: 10 Oct 2018 03:50
URI: http://raiithold.iith.ac.in/id/eprint/4480
Publisher URL: http://doi.org/10.1016/j.electacta.2018.09.171
OA policy: http://www.sherpa.ac.uk/romeo/issn/0013-4686/
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