Kumar, Sandeep and Nepak, Devadutta and Kansal, Mallikarjuna and Elumalai, Sasikumar
(2018)
Expeditious isomerization of glucose to fructose in aqueous media over sodium titanate nanotubes.
RSC Advances, 8 (53).
pp. 30106-30114.
ISSN 2046-2069
Abstract
Isomerization reaction of glucose to fructose over sodium titanate nanotubes (Na-TNTs) as a Lewis base catalyst was studied. Analytical instruments recorded the specific structural, textural and basic properties of the as-synthesized Na-TNTs. Furthermore, studying the catalytic isomerization performance of the Na-TNTs confirmed their high catalytic efficiency and suitability in aqueous media. The catalyst prompted rapid glucose isomerization within 2 min by achieving nearly half of the maximum yield, whereas with a prolonged reaction up to 15 min the maximum glucose conversion could be reached with 31.26% fructose yield and 65.26% selectivity under relatively lower operating conditions (100 °C and 10% wt catalyst dose). However, the recyclability performance of the catalyst was not impressive due to the accelerated leaching of cations and surface retention of carbonaceous content, resulting in ∼16% reduced yield after 4 runs. A simple regeneration technique using NaOH led to the initial catalytic activity being totally regained. Overall, a titania-based catalyst (preferably nanotube structured sodium titanate) was shown as a potential catalyst for large-scale demonstration of glucose isomerization to achieve high fructose productivity.
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