KOt Bu-Mediated Domino Isomerization and Functionalization of Aromatic Allylic Alcohols

Suchand, B and G, Satyanarayana (2017) KOt Bu-Mediated Domino Isomerization and Functionalization of Aromatic Allylic Alcohols. European Journal of Organic Chemistry, 2017 (26). pp. 3886-3895. ISSN 1434-193X (In Press)

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Abstract

Transition-metal- as well as ligand-free base-mediated domino isomerization and alkylation of allylic alcohols is presented. This protocol features the conversion of simple allylic alcohols into the corresponding ketones through isomerization in the presence of a simple base. Significantly, these in situ generated ketones subsequently undergo alkylation with styrenes as electrophiles, in a domino one-pot fashion, as an atom- and step-economical chemical process.

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IITH Creators:	IITH Creators ORCiD G, Satyanarayana UNSPECIFIED
Item Type:	Article
Uncontrolled Keywords:	Isomerization; Allylic compounds; Ketones; Domino reactions; Hydrogen transfer
Subjects:	Chemistry > Organic chemistry
Divisions:	Department of Chemistry
Depositing User:	Team Library
Date Deposited:	21 Jul 2017 05:06
Last Modified:	21 Jul 2017 05:06
URI:	http://raiithold.iith.ac.in/id/eprint/3412
Publisher URL:	https://doi.org/10.1002/ejoc.201700440
OA policy:	http://www.sherpa.ac.uk/romeo/issn/1434-193X/
Related URLs:	Google Scholar

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