Nano-sized Recyclable PdO Supported Carbon Nanostructures for Heck Reaction: Influence of Carbon Materials

Bhairi, L and Lodi, M and Ghosal, P and G, Satyanarayana and Ch, Subrahmanyam (2017) Nano-sized Recyclable PdO Supported Carbon Nanostructures for Heck Reaction: Influence of Carbon Materials. ChemistrySelect, 2 (9). pp. 2700-2707. ISSN 2365-6549

Full text not available from this repository. (Request a copy)

Abstract

Palladium oxide (PdO) supported carbon nanomaterials were designed and tested for Heck olefination of aryl halides. Various carbonaceous materials, such as single walled carbon nanotubes (SWCNT), multiwalled carbon nanotubes (MWCNT), carbon nanofiber (CNF), graphene oxide (GO) and reduced graphene oxide (RGO) were screened as support for PdO nanoparticles. The structural and phase formation of PdO on carbon materials was confirmed by X-ray diffraction, whereas, surface area and porous nature of the carbon materials was confirmed by N2 adsorption studies. The morphology of the materials was studied by electron microscopy. Among these catalysts, PdO/GO catalyst showed the best catalytic activity (turnover number 410 and frequency 205 h-1) for the Heck olefination and the catalyst was reused successfully up to 3 cycles, which confirms the true heterogeneous nature.

[error in script]

IITH Creators:	IITH Creators ORCiD G, Satyanarayana UNSPECIFIED Ch, Subrahmanyam https://orcid.org/0000-0002-2643-3854
Item Type:	Article
Uncontrolled Keywords:	Combustion Synthesis; Carbonaceous materials support; PdO; Heck reaction
Subjects:	Chemistry
Divisions:	Department of Chemistry
Depositing User:	Team Library
Date Deposited:	28 Mar 2017 07:12
Last Modified:	04 Dec 2017 05:46
URI:	http://raiithold.iith.ac.in/id/eprint/3116
Publisher URL:	https://doi.org/10.1002/slct.201602051
OA policy:	http://www.sherpa.ac.uk/romeo/issn/2365-6549/
Related URLs:	Google Scholar

Actions (login required)

View Item

Statistics for this ePrint Item