Rana, Ria and Panda, Tarun K
(2016)
Synthesis of N-Heterocyclic Carbene Adduct with BCl3 and its Reactivity with Amines And Zn (II) complexes Bearing N, O -Chelate Ligands: Synthesis and Characterization.
Masters thesis, Indian Institute of Technology Hyderabad.
Abstract
In the chapter 1 of my thesis I have described the synthesis of a Lewis adduct of 1, 3-bis (2,6-diisopropylphenyl) imidazole-2-ylidine (Dipp-NHC) with boron trichloride. The reaction of Dipp-NHC and BCl3 in equimolar ratio in toluene solution at room temperature for 24 h afforded the Lewis adduct Dipp-NHC.BCl3 (1). The compound 1 was further treated with 2, 4, 6- trimethylaniline to afford N,N’,N” - trismesitylboranetriamine [B(NH(2,4,6-Me3C6H2))3](2) in good yield. The compound 2 was characterized by 1H, 13C{1H}, 11B{1H}NMR spectroscopy.
[error in script]
| IITH Creators: |
| IITH Creators | ORCiD |
|---|
| Panda, Tarun K | http://orcid.org/0000-0003-0975-0118 |
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| Item Type: |
Thesis
(Masters)
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| Uncontrolled Keywords: |
trichloride, nitrogen-donor ligands, TD499 |
| Subjects: |
?? sub5.8 ?? |
| Divisions: |
Department of Chemistry |
| Depositing User: |
Library Staff
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| Date Deposited: |
05 May 2016 05:04 |
| Last Modified: |
22 May 2019 04:18 |
| URI: |
http://raiithold.iith.ac.in/id/eprint/2312 |
| Publisher URL: |
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| Related URLs: |
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