Synthesis of N-Heterocyclic Carbene Adduct with BCl3 and its Reactivity with Amines And Zn (II) complexes Bearing N, O -Chelate Ligands: Synthesis and Characterization

Rana, Ria and Panda, Tarun K (2016) Synthesis of N-Heterocyclic Carbene Adduct with BCl3 and its Reactivity with Amines And Zn (II) complexes Bearing N, O -Chelate Ligands: Synthesis and Characterization. Masters thesis, Indian Institute of Technology Hyderabad.

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Abstract

In the chapter 1 of my thesis I have described the synthesis of a Lewis adduct of 1, 3-bis (2,6-diisopropylphenyl) imidazole-2-ylidine (Dipp-NHC) with boron trichloride. The reaction of Dipp-NHC and BCl3 in equimolar ratio in toluene solution at room temperature for 24 h afforded the Lewis adduct Dipp-NHC.BCl3 (1). The compound 1 was further treated with 2, 4, 6- trimethylaniline to afford N,N’,N” - trismesitylboranetriamine [B(NH(2,4,6-Me3C6H2))3](2) in good yield. The compound 2 was characterized by 1H, 13C{1H}, 11B{1H}NMR spectroscopy.

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IITH Creators:
IITH CreatorsORCiD
Panda, Tarun Khttp://orcid.org/0000-0003-0975-0118
Item Type: Thesis (Masters)
Uncontrolled Keywords: trichloride, nitrogen-donor ligands, TD499
Subjects: ?? sub5.8 ??
Divisions: Department of Chemistry
Depositing User: Library Staff
Date Deposited: 05 May 2016 05:04
Last Modified: 22 May 2019 04:18
URI: http://raiithold.iith.ac.in/id/eprint/2312
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