Amidinate Ligands in Zinc coordination sphere: Synthesis and structural diversity

Anga, S and Banerjee, I and Panda, Tarun K (2016) Amidinate Ligands in Zinc coordination sphere: Synthesis and structural diversity. Journal of Chemical Sciences, 128 (6). pp. 867-873. ISSN 0974-3626

Preview

Text (Open access) document.pdf - Published Version Download (173kB) | Preview

Abstract

A one-pot reaction involving neosilyllithium and three different carbodiimides (RN=C=NR, R=cyclohexyl, isopropyl and tert-butyl) in diethyl ether, followed by the addition of anhydrous ZnCl2, afforded, in high yield, corresponding homoleptic zinc amidinate complexes having the molecular formulae [Zn{CyN =C(CH2SiMe3)NCy}2] (1), [Zn{ i PrN =C(CH2SiMe3)N i Pr}2] (2) and [Zn{ t BuN =C(CH2SiMe3) N t Bu}2] (3), respectively, and amidinato moieties in the zinc coordination sphere. Solid state structures of complexes 1-3 are reported thereafter - all the three complexes are isostructural, and each of them consists of two four-membered metallacycles.

[error in script]

IITH Creators:	IITH Creators ORCiD Panda, Tarun K http://orcid.org/0000-0003-0975-0118
Item Type:	Article
Uncontrolled Keywords:	Zinc, carbodiimides, amidinate, alkyl migration
Subjects:	Chemistry > Organic chemistry
Divisions:	Department of Chemistry
Depositing User:	Team Library
Date Deposited:	02 May 2016 04:10
Last Modified:	07 Sep 2017 10:48
URI:	http://raiithold.iith.ac.in/id/eprint/2303
Publisher URL:	https://doi.org/10.1007/s12039-016-1090-4
OA policy:	http://www.sherpa.ac.uk/romeo/issn/0974-3626/
Related URLs:	Google Scholar

Actions (login required)

View Item

Statistics for this ePrint Item