Paladugu, Suresh
(2014)
Imidazolium Carboxylate Based [C-H]δ+ Functionalized Discrete and Polymeric Coordination Assemblies: Synthesis and Characterization.
PhD thesis, Indian Institute of Technology Hyderabad.
Abstract
The construction of functionalized coordination polymers (FCPs) have been the subject of interest over the last few decades due to their fascinating architectures and versatile applications in catalysis, gas storage, separation, luminescence, electrical conductivity, magnetism and nonlinear optics. Suitable organic spacers, metal precursors and synthetic methodologies are essential criteria to design FCPs with different physical properties. In addition, non-covalent interactions such as hydrogen bond
s, π···π, M···π, C–H···π and anion···π interactions play a key role in FCPs to increase their dimensionality,
supramolecular topology and porosity.
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