Crystal Structure and Solid-State Properties of Discrete Hexa Cationic Trinuclear Zinc Triazole Cluster

Chatla, N B and Paladugu, S and Arruri, S and Das, P and G, Prabusankar (2015) Crystal Structure and Solid-State Properties of Discrete Hexa Cationic Trinuclear Zinc Triazole Cluster. Journal of Chemical Sciences, 127 (8). pp. 1369-1373. ISSN 0974-3626

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Abstract

A linear trinuclear cluster of the type [{Zn3(HTrz)6(H2O)6}6+(NO3 -)6(H2O)] (ZnT) has been synthesized by one-pot reaction between 1,2,4-triazole and Zn(NO3).6H2O. Molecule consists of three Zn2++ ions linearly connected by 1,2,4-triazole with tri-fold symmetry. The coordination geometry around the zinc centre is octahedral with zinc-zinc separation of 3.810 Å. The coordination environment of central Zn2++ ion is satisfied by nitrogen atoms of six 1,2,4-triazoles, while the geometry of terminal Zn2++ ions is fulfilled by nitrogen atoms of three 1,2,4-triazoles and three water molecules. The thermal and absorption properties of ZnThave been reported for the first time.

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IITH Creators:

IITH Creators	ORCiD
G, Prabusankar	http://orcid.org/0000-0003-1772-135X

Item Type:

Article

Uncontrolled Keywords:

Crystal structure; Ions; Molecules; Nitrogen; Synthesis (chemical) Absorption property; Cationic compounds; clusters; Coordination environment; Coordination geometry; Solid-state properties; Trinuclear cluster; trizole

Subjects:

Chemistry > Organic chemistry

Divisions:

Department of Chemistry

Depositing User:

Library Staff

Date Deposited:

27 May 2015 07:03

Last Modified:

12 Sep 2017 06:21

URI:

http://raiithold.iith.ac.in/id/eprint/1534