Simple, copper(I)-catalyzed oxidation of benzylic/allylic alcohols to carbonyl compounds: Synthesis of functionalized cinnamates in one pot

Reddy, A G K and Mahendar, L and G, Satyanarayana (2014) Simple, copper(I)-catalyzed oxidation of benzylic/allylic alcohols to carbonyl compounds: Synthesis of functionalized cinnamates in one pot. Synthetic Communications, 44 (14). pp. 2076-2087. ISSN 0039-7911

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Abstract

An environmentally benign [Cu(I)]-catalyzed oxidation of activated (benzylic/allylic) alcohols to the corresponding carbonyl compounds is presented. Interestingly, the reaction was also compatible with benzylic alcohols containing ortho-bromo substituents on the aromatic ring without competing with the expected intermolecular Buchwald coupling. Significantly, the catalytic system enables the synthesis of cinnamate-esters in a sequential domino one-pot fashion via oxidation followed by Wittig-Horner protocol.

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IITH Creators:	IITH Creators ORCiD G, Satyanarayana UNSPECIFIED
Item Type:	Article
Uncontrolled Keywords:	Allylic alcohols; benzylic alcohols; carbonyl compounds; cinnamates; oxidation; [Cu]-catalysis
Subjects:	?? sub5.8 ??
Divisions:	Department of Chemistry
Depositing User:	Team Library
Date Deposited:	02 Dec 2014 09:13
Last Modified:	06 Jan 2016 07:19
URI:	http://raiithold.iith.ac.in/id/eprint/1109
Publisher URL:	http://dx.doi.org/10.1080/00397911.2013.879389
OA policy:	http://www.sherpa.ac.uk/romeo/issn/0039-7911/
Related URLs:	Google Scholar

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