Visible-Light-Mediated Photocatalytic Oxidative C–C Bond Cleavage of Geminal Diazides: An Approach to Oxamates

Sharada, D S and Katta, Narenderreddy and Murugan, Arumugavel and et al, . (2021) Visible-Light-Mediated Photocatalytic Oxidative C–C Bond Cleavage of Geminal Diazides: An Approach to Oxamates. SynOpen, 05 (02). pp. 152-157. ISSN 2509-9396

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Abstract

Photoredox catalysis has received great attention in both academia and industry and remarkable progress has been made over the past decade. Now, it has been shown that a visible-light-mediated oxidative C-C bond cleavage of geminal diazides can be induced by organic dye catalysis for the synthesis of oxamates. A mechanistic study, confirmed by control experiments, indicates that this proceeds through single-electron transfer (SET). This methodology can be applied to convert a wide array of geminal diazides into oxamates. © 2021. The Author(s).

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IITH Creators:

IITH Creators	ORCiD
Sharada, D S	UNSPECIFIED

Item Type:

Article

Additional Information:

We gratefully acknowledge the Council of Scientific and Industrial Research (02(0297)/17/EMR-II), Government of India and the Indian Institute of Technology Hyderabad (IITH) for financial support. N.R.K. thanks the Indian Institute of Technology Hyderabad (IITH) and the Science and Engineering Research Board, Department of Science and Technology, Ministriy of Science and Technology, India (DST-SERB), and A.V.M thanks the University Grants Committee (UGC) for the award of research rellowships.Council ofScieniicfandIndustal Reeach, India(02(0297)/17/EMRII)ScienceandEngineeingReseachBoadUnivesiytGansCommiete

Uncontrolled Keywords:

C-C cleavage; oxamates; photoredox

Subjects:

Chemistry

Divisions:

Department of Chemistry

Depositing User:

. LibTrainee 2021

Date Deposited:

07 Oct 2022 05:23

Last Modified:

07 Oct 2022 05:23