Metal/Non‐Metal Catalyzed Activation of Organic Nitriles

Das, Suman and Maity, Jyotirmoy and Panda, Tarun K (2022) Metal/Non‐Metal Catalyzed Activation of Organic Nitriles. Wiley.

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Abstract

Nitrile activation is a prominent topic in recent developments in chemistry, especially in organic, inorganic, biological chemistry, as well as in the natural synthesis of products and in the pharmaceutical industry. The activation of nitriles using both metal and non-metal precursors has attracted several researchers, who are exploring newer ways to synthesize novel compounds. Nitrile activation can be achieved by combining various catalytic double hydroelementation reactions, such as hydrosilylation, hydroboration, and hydrogenation of organonitriles using silanes, pinacolborane, and other sources of hydrogen. These methodologies have garnered considerable attention since they are effective in the reduction of organonitriles, whose end products are extensively applied in synthetic organic chemistry. In this review, we summarize the development of selective hydroborylation, hydrosilylation, dihydroborysilylation, and hydrogenation of organonitriles, as well as their reaction mechanisms and the role of metal complexes in the catalytic cycles. This review article explains various synthetic methodologies applied toward the reduction of organonitriles into corresponding amines.

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IITH Creators:

IITH Creators	ORCiD
Panda, Tarun K	http://orcid.org/0000-0003-0975-0118

Item Type:

Other

Additional Information:

This work was financially supported by the Indian Institute of Technology Hyderabad. J.M. is grateful to Prof. (Dr.) John Varghese, Principal, St. Stephen's College, and Dr. Vibha Sharma, Head of Department, Department of Chemistry, St. Stephen's College, for their encouragement and support.

Uncontrolled Keywords:

HYDROSILYLATION,HYDROBORATION,COMPLEXES

Subjects:

Chemistry

Divisions:

Department of Chemistry

Depositing User:

. LibTrainee 2021

Date Deposited:

26 Sep 2022 04:56

Last Modified:

26 Sep 2022 04:56