Total synthesis of a novel oxa-bowl natural product paracaseolide A via a 'putative' biomimetic pathway

Vasamsetty, L and Khan, Faiz Ahmed and Mehta, G (2013) Total synthesis of a novel oxa-bowl natural product paracaseolide A via a 'putative' biomimetic pathway. Tetrahedron Letters, 54 (27). pp. 3522-3525. ISSN 0040-4039

Full text not available from this repository. (Request a copy)

Abstract

A total synthesis of bioactive tetracyclic natural product paracaseolide A, embodying an architecturally unusual oxa-bowl framework, has been accomplished from commercially available 5-methyl-2-furfural. The key step involving a thermal [4+2]-dimerization of an appropriately crafted 5-methyl-3- alkenylbutenolide is shown to proceed in a stepwise manner

[error in script]

IITH Creators:	IITH Creators ORCiD Khan, Faiz Ahmed UNSPECIFIED
Item Type:	Article
Uncontrolled Keywords:	3-Alkenylbutenolide; [4+2]-Type dimerization; Biomimetic; Singlet oxygen; Suzuki coupling
Subjects:	Chemistry
Divisions:	Department of Chemistry
Depositing User:	Team Library
Date Deposited:	29 Nov 2014 08:53
Last Modified:	21 Sep 2017 07:21
URI:	http://raiithold.iith.ac.in/id/eprint/1059
Publisher URL:	https://doi.org/10.1016/j.tetlet.2013.04.097
OA policy:	http://www.sherpa.ac.uk/romeo/issn/0040-4039/
Related URLs:	Google Scholar

Actions (login required)

View Item

Statistics for this ePrint Item